Abstract

Research Article

Fabrication of novel Co3O4@GO/La2O3 nanocomposites as efficient, innovative and recyclable nanocatalysts for the synthesis of quinazolinone derivatives under solvent-free conditions

Fereshteh Javidfar and Manoochehr Fadaeian*

Published: 02 September, 2022 | Volume 6 - Issue 1 | Pages: 043-047

For the first time, this research has developed an efficient and novel approach to high to excellent yields for synthesizing Quinazolinone derivatives. Also, the synthesis of Quinazolinone derivatives has been carried out in the presence of Co3O4@GO/La2O3 nanocomposite as a novel heterogeneous catalyst and a green under solvent-free conditions and in a short time and excellent yields for the first time. Various structural and morphological characteristics of the nanocatalyst were employed for the catalyst characterization, such as FT-IR, XRD, FE-SEM, EDX and VSM analyses. All characterization data were checked with each other so that the structure of the nanocatalyst was exactly characterized. The reactions were carried out in the presence of a low amount of nanocatalyst at 100 °C under solvent-free conditions for a short period of time. The proposed nanocomposite exhibits excellent catalytic activity. One of the most important advantages of this method is easy magnetic nanocatalyst separation, green condition, excellent recoverability and easy workup.

Read Full Article HTML DOI: 10.29328/journal.aac.1001030 Cite this Article Read Full Article PDF

Keywords:

Quinazolinone derivatives; Heterogeneous; Lanthanum; Magnetic nanocomposite

References

  1. Al-Toum R, Bdour S, Ayyash H. Adenovirus Infections in Jordanian Hospitalized Paediatric Patients: Prevalence and Clinical Features. J Med J. 2009; 43(3):171–179.
  2. Ighilahriz-Boubchir K, Boutemeur-Kheddis B, Rabia C, Makhloufi-Chebli M, Hamdi M, Silva AMS. Recyclable Keggin Heteropolyacids as an Environmentally Benign Catalyst for the Synthesis of New 2-Benzoylamino-N-phenyl-benzamide Derivatives under Microwave Irradiations at Solvent-Free Conditions and the Evaluation of Biological Activity. Molecules. 2017 Dec 21;23(1):8. doi: 10.3390/molecules23010008. PMID: 29267237; PMCID: PMC5943967.
  3. Shi P, Dai X, Zheng H, Li D, Yao W, Hu Ch. Synergistic catalysis of Co3O4 and graphene oxide on Co3O4/GO catalysts for degradation of Orange II in water by advanced oxidation technology based on sulfate radicals. Chem. Eng. J. 2014; 240: 264–270.
  4. Javidfar F, Fadaeian M, Safaie Ghomi J. Synthesis of Fe3O4@GO Nanocomposites Modified with La2O3 Nanoparticles as an Efficient Catalyst for Selective Oxidation of Aromatic Alcohols to Aldehydes. Polycycl, Aromat. Compd. 2021.
  5. Can K, Fang L, Hui S, Zhou Zh, Benjie Z, Wei Li. Co3O4/GO catalyst as efficient heterogeneous catalyst for degradation of wastewater containing polyacrylamide (PAM). Water Cycle. 2021.
  6. Islami M, Zarrabi A, Tada S, Kawamoto M, Isoshima T, Ito Y. Controlled quercetin release from high-capacity-loading hyperbranched polyglycerol-functionalized graphene oxide. Int J Nanomedicine. 2018 Oct 5;13:6059-6071. doi: 10.2147/IJN.S178374. PMID: 30323593; PMCID: PMC6179725.
  7. Gadolin J. Examination of a black, dense mineral from the Ytterby Quarry in Roslagen. Proceedings of the Royal Academy (Stockholm, new series) (in the original Swedish: Undersökning af en svart tung Stenart ifrån Ytterby Stenbrott i Roslagen. K Vetenskaps-akad nya handl). 1794; 15: 137-155.
  8. Javidfar F, Fadaeian M, Ghomi JS. La(OH)3nanoparticles immobilized on Fe3O4@chitosan composites as novel magnetic nanocatalysts for sonochemical oxidation of benzyl alcohol to benzaldehyde. RSC Adv. 2021 Nov 8;11(57):35988-35993. doi: 10.1039/d1ra05848g. PMID: 35492745; PMCID: PMC9043185.
  9. Khosropour AR, Mohammadpoor-Baltork I, Ghorbankhani H. Bi (TFA)3–[nbp]FeCl4: a new, efficient and reusable promoter system for the synthesis of 4(3H)-quinazolinone derivatives.Tetrahedron. Lett. 2006; 47(21): 3561–3564.
  10. Narasimhulu M, Mahesh KC, Reddy TS, Rajesh K, Venkateswarlu Y. Lanthanum (III) nitrate hexahydrate or p-toluenesulfonic acid catalyzed one-pot synthesis of 4(3H)-quinazolinones under solvent-free conditions. Lett. 2006; 47(26): 4381–4383.
  11. Lin CC, Guo Y, Vela J. Microstructure Effects on the Water Oxidation Activity of Co3O4/Porous Silica Nanocomposites. ACS Catal. 2015; 5(2): 51037–1044.
  12. Zhou X, Shi J, Qin PH, Fan YF, Min JC, Yao YL, WF. Synthesis of Co3O4/graphene composite catalysts through CTAB-assisted method for orange II degradation by activation of peroxymonosulfate. J. Mater. Sci. Mater. Electron. 2016; 27: 1020–1030.
  13. Abdoli M, Nami N, Hossaini Z. One-Pot Synthesis of Spiro-Acridine/Indoline and Indoline Derivatives Using (MWCNTs) - COOH/La2O3 Hybrid as an Effective Catalyst. J. Heterocycl. Chem. 2020; 58(2): 523–33.
  14. Aftab U, Tahira A, Gradone A, Morandi V, Abro MI, Baloch MM, Ibupoto ZH. Int. J. Hydrog. Energy. 2021; 46(13): 9110–9122.
  15. Vinodha G, Shima PD, Cindrella L. Mesoporous Magnetite Nanoparticle-Decorated Graphene Oxide Nanosheets for Efficient Electrochemical Detection of Hydrazine. J. Mater. Sci. 2019; 54: 4073–88.
  16. Tang B, Ge J, Wu C, Zhuo L, Niu J, Chen Z, Shi Z, Dong Y. Sol–Solvothermal Synthesis and Microwave Evolution of La (OH)3 Nanorods to La2O3 Nanotechnology. 2004; 15(9):1273–6.
  17. Dai X, Virgil S. Synthesis of 2-heterosubstituted quinazolinone atropisomeric phosphine ligands by direct lithiation of a 2-unsubstituted quinazolinone system. Tetrahedron: Asymmetry. 1999; 10(1): 25–29.
  18. Abbas SY, El-Bayouki KAM, Basyouni WM, Mostafa EA. New series of 4(3H)-quinazolinone derivatives: syntheses and evaluation of antitumor and antiviral activities. Med Chem Res. 2017; 27: 571–582.
  19. Norouzi FH, Foroughifar N, Khajeh-Amiri A, Pasdar H. A novel superparamagnetic powerful guanidine-functionalized γ-Fe2O3based sulfonic acid recyclable and efficient heterogeneous catalyst for microwave-assisted rapid synthesis of quinazolin-4(3H)-one derivatives in Green media. RSC Adv. 2021 Sep 7;11(48):29948-29959. doi: 10.1039/d1ra05560g. PMID: 35480261; PMCID: PMC9040894.

Figures:

Figure 1

Figure 1

Figure 1

Figure 2

Figure 1

Figure 3

Figure 1

Figure 4

Figure 1

Figure 5

Figure 1

Figure 6

Figure 1

Figure 7

Figure 1

Figure 8

Figure 1

Figure 9

Similar Articles

Recently Viewed

Read More

Most Viewed

Read More

Help ?